Error Compiling SharePoint Workflow in Dev Server.

If any one of have problem compiling the SharePoint 2010 Workflow (Sequential and State Machine) in you Dev Server. And if the Error is this

Even for the empty workflow its giving this error.

Error 1 The "CompileWorkflowTask" task failed unexpectedly.
System.NotSupportedException: The given path's format is not supported.
   at System.Security.Util.StringExpressionSet.CanonicalizePath(String path, Boolean needFullPath)
   at System.Security.Util.StringExpressionSet.CreateListFromExpressions(String[] str, Boolean needFullPath)
   at System.Security.Permissions.FileIOPermission.AddPathList(FileIOPermissionAccess access, AccessControlActions control, String[] pathListOrig, Boolean checkForDuplicates, Boolean needFullPath, Boolean copyPathList)
   at System.Security.Permissions.FileIOPermission..ctor(FileIOPermissionAccess access, String[] pathList, Boolean checkForDuplicates, Boolean needFullPath)
   at System.IO.Path.GetFullPath(String path)
   at System.CodeDom.Compiler.TempFileCollection.EnsureTempNameCreated()
   at System.CodeDom.Compiler.TempFileCollection.AddExtension(String fileExtension, Boolean keepFile)
   at System.Workflow.ComponentModel.Compiler.CompileWorkflowTask.Execute()
   at Microsoft.Build.BackEnd.TaskExecutionHost.Microsoft.Build.BackEnd.ITaskExecutionHost.Execute()
   at Microsoft.Build.BackEnd.TaskBuilder.ExecuteInstantiatedTask(ITaskExecutionHost taskExecutionHost, TaskLoggingContext taskLoggingContext, TaskHost taskHost, ItemBucket bucket, TaskExecutionMode howToExecuteTask, Boolean& taskResult) stateWorkflow1

Check this Thread in MSDN Forum.

http://social.technet.microsoft.com/Forums/en-US/sharepoint2010programming/thread/74975cb4-20f9-4a3f-bb41-74382eecc5bb/#dd666781-46fb-4bb2-b8e8-cf49a4ebfa4b